KEVOS® MAKEOS · Engineering

Vapour-Compression Refrigeration or Heat Pump Cycle Check (COP from State Enthalpies, Carnot Limit)

From the refrigerant enthalpies at the compressor inlet, isentropic discharge and condenser outlet, what refrigerant flow, compressor power and COP does this cycle give, how close is it to the Carnot limit, and does it meet the COP you need?

Single-stage vapour-compression refrigeration or heat-pump cycle from the refrigerant enthalpies at the compressor inlet, after isentropic compression and at the condenser outlet: the refrigerating effect, the actual compressor work, the heat rejected, the refrigerant flow and compressor power for the duty, the COP as a refrigerator and as a heat pump, and the comparison with the reversed-Carnot COP, against the COP you need.

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How this tool works

Inputs, units and where to find them

InputUnitTypical source
Duty you are sizing forchoiceCooling sizes the refrigerant flow on the heat absorbed; heating sizes it on the heat delivered.
Cooling or heating dutykWThe cooling load (cooling) or the heat to be delivered (heating), from your load calculation.
Refrigerant state enthalpies (from tables or software, one reference state)
Enthalpy at the compressor inlet (evaporator outlet)kJ/kgRefrigerant enthalpy leaving the evaporator: saturated or superheated vapour at the evaporating pressure, from refrigerant tables or property software.
Enthalpy after isentropic compression to condensing pressurekJ/kgEnthalpy at the condensing pressure and the same entropy as the compressor inlet, from the superheated table or software.
Enthalpy at the condenser outlet (before the expansion valve)kJ/kgEnthalpy of the liquid leaving the condenser: saturated or subcooled liquid at the condensing pressure.
Compressor isentropic efficiency%Compressor isentropic efficiency from the compressor maker’s data at this pressure ratio.
Temperatures and target
Evaporating temperature°CEvaporating (saturation) temperature in the evaporator.
Condensing temperature°CCondensing (saturation) temperature in the condenser.
COP required for the selected dutyThe COP the duty must reach, for example from the specification, an energy target or the existing plant.

What each input means

Open an input to see what it is, its units, the worked example and the common mistakes, with a small diagram.

What this means: Duty you are sizing for
Illustration: Duty you are sizing forThe options for Duty you are sizing for, with the one currently selected highlighted.Cooling (refrigerator, chiller or air condi…Heating (heat pump)Example: Cooling (refrigerator, ch…Duty you are sizing for
What it is
Whether the duty you enter is heat removed from the cold side (cooling) or heat delivered to the warm side (heating), which sets the COP reported and the refrigerant flow.
Units and format
Choose one of 2 options from the list: Cooling (refrigerator, chiller or air conditioner); Heating (heat pump).
Example
The form opens with “Cooling (refrigerator, chiller or air conditioner)” selected as a worked example. Choose the option that matches your case.
Effect on the result
Switches the duty, the COP and the Carnot limit between the refrigerator and heat-pump forms.
Get it right
A reverse-cycle air conditioner is a heat pump when heating; enter the heating output in that case.
What this means: Cooling or heating duty
Illustration: Cooling or heating dutyA motor driving a shaft; Cooling or heating duty is the rate at which it does work, energy per second.QExample: 10 kWCooling or heating duty
What it is
The rate of heat the system must remove (cooling) or deliver (heating), which fixes the refrigerant mass flow and compressor power.
Units and format
Enter a number in kW: kilowatts. The form accepts 0.001 kW to 100000 kW. Required: the tool does not calculate until every input is valid.
Example
The form opens with 10 kW as a worked example. It is an illustration, not a recommended value: replace it with your own figure.
Effect on the result
Refrigerant flow, compressor power and both heat flows rise in proportion; COP does not change.
Get it right
Use the load at the design condition, including any safety allowance you normally add.

Refrigerant state enthalpies (from tables or software, one reference state)

What this means: Enthalpy at the compressor inlet (evaporator ou…
Illustration: Enthalpy at the compressor inlet (evaporator outlet)A store filling up with energy; Enthalpy at the compressor inlet (evaporator outlet) is the total amount of work or heat involved.h₁Example: 395 kJ/kgEnthalpy at the compressor inlet (evaporator…
What it is
The specific enthalpy of the refrigerant vapour entering the compressor, at the evaporator outlet, including any superheat.
Units and format
Enter a number in kJ/kg: kJ/kg. The form accepts -500 kJ/kg to 3000 kJ/kg. Required: the tool does not calculate until every input is valid.
Example
The form opens with 395 kJ/kg as a worked example. It is an illustration, not a recommended value: replace it with your own figure.
Effect on the result
A higher value increases the refrigerating effect per kilogram for the same throttled liquid.
Get it right
Read it from the same table or program as the other two enthalpies; reference states differ between sources.
What this means: Enthalpy after isentropic compression to conden…
Illustration: Enthalpy after isentropic compression to condensing pressureA store filling up with energy; Enthalpy after isentropic compression to condensing pressure is the total amount of work or heat involved.h₂ₛExample: 425 kJ/kgEnthalpy after isentropic compression to cond…
What it is
The enthalpy the refrigerant would have leaving an ideal compressor: at the condensing pressure and the same entropy as at the compressor inlet.
Units and format
Enter a number in kJ/kg: kJ/kg. The form accepts -500 kJ/kg to 3000 kJ/kg. Required: the tool does not calculate until every input is valid.
Example
The form opens with 425 kJ/kg as a worked example. It is an illustration, not a recommended value: replace it with your own figure.
Effect on the result
A higher value means more compressor work per kilogram and a lower COP.
Get it right
Find it in the superheated table at the condensing pressure using the inlet entropy, or with property software.
What this means: Enthalpy at the condenser outlet (before the ex…
Illustration: Enthalpy at the condenser outlet (before the expansion valve)A store filling up with energy; Enthalpy at the condenser outlet (before the expansion valve) is the total amount of work or heat involved.h₃Example: 255 kJ/kgEnthalpy at the condenser outlet (before the…
What it is
The specific enthalpy of the liquid refrigerant leaving the condenser, which passes unchanged through the expansion valve into the evaporator.
Units and format
Enter a number in kJ/kg: kJ/kg. The form accepts -500 kJ/kg to 3000 kJ/kg. Required: the tool does not calculate until every input is valid.
Example
The form opens with 255 kJ/kg as a worked example. It is an illustration, not a recommended value: replace it with your own figure.
Effect on the result
A lower value raises the refrigerating effect and the COP.
Get it right
Subcooling lowers this value; use the liquid temperature measured before the valve where you can.
What this means: Compressor isentropic efficiency
Illustration: Compressor isentropic efficiencyInput on the left and useful output on the right with the loss split off; Compressor isentropic efficiency is output divided by input.inputuseful outputlossη_cExample: 75%Compressor isentropic efficiency
What it is
The ideal (isentropic) compression work divided by the work the real compressor needs for the same pressure rise.
Units and format
Enter a number in %: percent: the number is read as a percentage, so type 8 for 8 %. The form accepts 20% to 100%. Required: the tool does not calculate until every input is valid.
Example
The form opens with 75% as a worked example. It is an illustration, not a recommended value: replace it with your own figure.
Effect on the result
A lower efficiency raises the compressor work and discharge enthalpy and lowers the COP.
Get it right
Take it from the compressor maker’s data at your pressure ratio; it is not the motor efficiency.

Temperatures and target

What this means: Evaporating temperature
Illustration: Evaporating temperatureA thermometer whose level rises with Evaporating temperature; the level follows the value you type.T_eExample: -10 °CEvaporating temperature
What it is
The saturation temperature of the refrigerant boiling in the evaporator, the cold end used for the reversed-Carnot COP.
Units and format
Enter a number in °C: degrees Celsius. The form accepts -100 °C to 50 °C. Required: the tool does not calculate until every input is valid.
Example
The form opens with -10 °C as a worked example. It is an illustration, not a recommended value: replace it with your own figure.
Effect on the result
Raising it raises the reversed-Carnot COP, so the same cycle COP becomes a smaller share of the limit.
Get it right
Use the saturation temperature at the suction pressure, not the air or water temperature leaving the evaporator.
What this means: Condensing temperature
Illustration: Condensing temperatureA thermometer whose level rises with Condensing temperature; the level follows the value you type.T_cExample: 40 °CCondensing temperature
What it is
The saturation temperature of the refrigerant condensing in the condenser, the warm end used for the reversed-Carnot COP.
Units and format
Enter a number in °C: degrees Celsius. The form accepts -50 °C to 150 °C. Required: the tool does not calculate until every input is valid.
Example
The form opens with 40 °C as a worked example. It is an illustration, not a recommended value: replace it with your own figure.
Effect on the result
Lowering it raises the reversed-Carnot COP, so the same cycle COP becomes a smaller share of the limit.
Get it right
Use the saturation temperature at the discharge pressure; it sits above the air or water it rejects heat to.
What this means: COP required for the selected duty
Illustration: COP required for the selected dutyTwo wheels of different sizes linked together; COP required for the selected duty compares one with the other.COPExample: 3COP required for the selected duty
What it is
The coefficient of performance the selected duty must reach: heat moved per unit of compressor work, as a refrigerator or as a heat pump according to the duty chosen.
Units and format
Enter a plain number with no unit. The form accepts 0.1 to 50. Required: the tool does not calculate until every input is valid.
Example
The form opens with 3 as a worked example. It is an illustration, not a recommended value: replace it with your own figure.
Effect on the result
Only moves the pass or fail line of the COP check.
Get it right
Compare like with like: this cycle COP excludes motor, fan and pump power, so it is higher than a system rating.

Method and formulas

  1. Throttling is at constant enthalpy, so h₄ = h₃; refrigerating effect q_L = h₁ − h₄.
  2. Compressor work w = (h₂ₛ − h₁) ÷ η_c; actual discharge h₂ = h₁ + w; heat rejected q_H = h₂ − h₃ = q_L + w.
  3. COP_R = q_L ÷ w and COP_HP = q_H ÷ w; refrigerant flow ṁ = duty ÷ q_L (cooling) or duty ÷ q_H (heating); compressor power = ṁ w.
  4. Reversed-Carnot limits with T in kelvin: COP_R,max = T_L ÷ (T_H − T_L), COP_HP,max = T_H ÷ (T_H − T_L); second-law efficiency = COP ÷ COP_max.
  5. Example: enthalpies of 395, 425 and 255 kJ/kg with a 75 % compressor give a COP of 3.5 for cooling, 2.857 kW of compressor power and 0.0714 kg/s of refrigerant for 10 kW, 66.5 % of the reversed-Carnot COP of 5.263 between −10 °C and 40 °C.

Limitations

  • One-stage cycle with an adiabatic compressor and expansion valve; no pressure drops in pipes and heat exchangers, no heat gains to the suction line, and no motor, drive or fan power. Real system COPs are lower.
  • The enthalpies must come from one table or program with one reference state; mixing sources gives wrong results without any warning.
  • A screening calculation, not a plant selection; the equipment maker’s data, AS/NZS 5149 and licensed refrigeration trades govern real systems.
  • Example values are illustrations shaped like a common refrigerant cycle. Replace them with values for your refrigerant and conditions.

Typical uses

  • Check a chiller, cold room or heat pump selection against a COP target
  • Work out refrigerant mass flow and compressor power from a duty and refrigerant table values
  • Show how much of the Carnot limit a real cycle reaches at a given lift

Who it is for

  • Refrigeration and air-conditioning engineers and technicians
  • Mechanical services designers
  • Energy auditors

What you get

  • Refrigerating effect, compressor work and heat rejected per kilogram
  • Actual discharge enthalpy
  • Refrigerant mass flow, compressor power and both heat flows
  • COP as a refrigerator and heat pump, reversed-Carnot COP and second-law efficiency
  • COP against the target

Interpreting the result

  • The heat-pump COP is always the refrigerator COP plus one for the same cycle, because the compressor work also ends up as heat delivered.
  • Each degree less lift between evaporating and condensing temperatures raises the Carnot COP, which is why clean condensers and correct evaporating temperatures save energy.

Before relying on the result

  • Check the result against the compressor maker’s rated capacity and power at the same evaporating and condensing temperatures.
  • Measure suction and discharge pressures and temperatures on the running plant to confirm the states assumed.

References

  • Çengel Y. A. and Boles M. A., Thermodynamics: An Engineering Approach, 5th edition (McGraw-Hill, 2006), chapter 11 (sections 11-1 to 11-4: COP, reversed Carnot cycle, ideal and actual vapour-compression cycles) and section 6-12. Method reference; no tables, figures or examples are reproduced.
  • AS/NZS 5149 Refrigerating systems and heat pumps: safety and environmental requirements (named by number and scope only).
  • NIST Chemistry WebBook, thermophysical properties of fluid systems (webbook.nist.gov): one source of refrigerant enthalpies; note its reference state.

Learn the Concepts Behind This Tool

These KEVOS® Library readings explain the method this tool uses, with worked examples.

KEVOS® tools are screening and decision-support utilities. Verify important financial, engineering, safety, legal or operational decisions using appropriate professional standards and your organisation’s approved data.

Open the Vapour-Compression Refrigeration or Heat Pump Cycle Check (COP from State Enthalpies, Carnot Limit) calculator